135369-23-2

Basic information

• Product Name: Benzenepropanoic acid, a-[(diethylamino)methyl]-b-hydroxy-, 2-methylpropyl ester
• CAS NO: 135369-23-2
• Molecular Formula: C18H29NO3
• Molecular Weight: 307.433
• Mol File: 135369-23-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenepropanoic acid, a-[(diethylamino)methyl]-b-hydroxy-, 2-methylpropyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanoic acid, a-[(diethylamino)methyl]-b-hydroxy-, 2-methylpropyl ester(135369-23-2)
• EPA Substance Registry System: Benzenepropanoic acid, a-[(diethylamino)methyl]-b-hydroxy-, 2-methylpropyl ester(135369-23-2)

Safety Data

• Hazardous Substances Data: 135369-23-2(Hazardous Substances Data)

Upstream product

• 106-63-8 isobutyl acrylate 
• 4419-47-0 tetrakis(diethylamino)titanium 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Tandem conjugate addition-aldol reaction to α,β-unsaturated esters and ketones using titanium amide

Titanium dialkylamide, readily available, adds to a α,β-unsaturated esters and ketones in a conjugate addition mode to give ester and ketone enolates, respectively, which are successively quenched with electrophiles such as aldehydes and acetals. The aldol products can be readily converted to the corresponding deaminated or dehydrated derivatives selectively.