135413-75-1Relevant academic research and scientific papers
Topochemical induction to an alternating zigzag-linear and "syndiotactic" chain structure in the course of a [2+2] photoreaction of alkyl α-cyano-4-[2-(2-pyridyl)ethenyl]cinnamate crystals
Chung, Chan-Moon,Kunita, Akira,Hayashi, Keiichi,Nakamura, Fumihiko,Saigo, Kazuhiko,Hasegawa, Masaki
, p. 7316 - 7322 (2007/10/02)
Methyl and ethyl α-cyano-4-[2-(2-pyridyl)ethenyl]cinnamate (1a and 1b) crystals are highly photoreactive and are converted by a [2+2] photocycloaddition reaction into dimers (2a and 2b) in high yields or upon further photoirradiation into a tricyclic dime
The Formation of an Alternating Zigzag and Linear Chain Structure with Topochemical Induction into the Racemate Crystal
Hasegawa, Masaki,Kunita, Akira,Chung, Chanmoon,Hayashi, Keiichi,Sato, Sadao
, p. 641 - 644 (2007/10/02)
Methyl and ethyl α-cyano-4-cinnamate crystals were highly photoreactive and formed the cycloadduct having an alternating zigzag and linear chain structures accompained with topochemical induction of the two chiralities alternatively in the chain from the β-type achiral crystal of prochiral molecules.
