135423-56-2Relevant academic research and scientific papers
Preparative bioorganic chemistry; XIV. Preparation of (2S,3S)-1-phenylthio-2,3-pentanediol and (2S,3S)-1-phenylsulfonyl-2,3-pentanediol by yeast reduction of the corresponding diketones, and conversion of the former to (+)-endo-brevicomin
Mori,Ishikura,Seu
, p. 487 - 490 (2007/10/02)
(2S,3S)-1-Phenylthio-2,3-pentanediol (2) and (2S,3S)-1-phenylsulfonyl-2,3-pentanediol (16) were prepared by reducing the corresponding diketones, 6 and 15, with baker's yeast. Conversion of 2 to (3S,4R)-8-nonene-3,4-diol (13), the key intermediate for the
