1354547-75-3Relevant academic research and scientific papers
Cyano and Thiocyanato-derivatives of the Hexachlorophosphate Ion (PCl6(1-))
Dillon, Keith B.,Platt, Andrew W. G.
, p. 1199 - 1204 (2007/10/02)
The preparation and identification in solution of several new cyano- and thiocyanato-derivatives of the hexachlorophosphate (PCl6(1-)) ion are described.The cyano-complexes (1-) (n = 1-3) and the hexathiocyanatophosphate ion P(NCS)6(1-) have been isolated as tetra-n-alkylammonium salts and further characterised by elemental analysis, (31)P n.m.r., and (in some cases) vibrational spectroscopy.The mer isomer of the (1-) ion has been obtained pure and the fac isomer in a less pure state (ca. 3:1 fac:mer) by different preparative routes.Isomeric configurations in the chlorothiocyanatophosphate series (1-) have been assigned on the basis of the pairwise interaction method.
