1354550-47-2Relevant academic research and scientific papers
Isolation and characterization of main group and late transition metal complexes using orthometallated imine ligands
Beck, John F.,Schmidt, Joseph A. R.
, p. 860 - 870 (2012/03/07)
Several late transition metal and main group orthometallated imine complexes were synthesized by utilizing ortholithiated imine precursors. Magnesium, aluminum, zinc, copper(i), and tin(iv) complexes were isolated and characterized. Subsequent reactions with electrophiles such as Ph 2PCl, MeI and I2 yielded several functionalized products, including a new iminophosphine ligand and its corresponding copper(i) complex. The coordination modes of the orthometallated imine ligands, as well as the structures of the metal complexes, were studied in the solid state using small molecule X-ray diffraction when possible.
