1354658-69-7Relevant academic research and scientific papers
Ligand-controlled, tunable silver-catalyzed C-H amination
Alderson, Juliet M.,Phelps, Alicia M.,Scamp, Ryan J.,Dolan, Nicholas S.,Schomaker, Jennifer M.
, p. 16720 - 16723 (2014)
The development of readily tunable and regioselective C-H functionalization reactions that operate solely through catalyst control remains a challenge in modern organic synthesis. Herein, we report that simple silver catalysts supported by common nitrogenated ligands can be used to tune a nitrene transfer reaction between two different types of C-H bonds. The results reported herein represent the first example of ligand-controlled and site-selective silver-promoted C-H amination.
