135468-39-2Relevant academic research and scientific papers
Functionality Transfer from C6 to C8 in Sesquiterpenes. Synthesis of 8-epi-Ivangustin and 8-epi-Isoivangustin from Santonin
Blay, Gonzalo,Cardona, M. Luz,Garcia, Begona,Pedro, Jose R.
, p. 6172 - 6175 (1991)
The short-range functionality transfer from C6 to C8 in eudesmane framework was reported.Santonin (1) was converted into 8-epi-ivangustin (16) and 8-epi-isoivangustin (18) via synthetic pathway involving the aforementioned functionality transfer and treatment of an intermediate diselenide 9 with m-CPBA.
