Functionality Transfer from C6 to C8 in Sesquiterpenes. Synthesis of 8-epi-Ivangustin and 8-epi-Isoivangustin from Santonin

DOI: 10.1021/jo00021a040

Source and publish data:

Journal of Organic Chemistry p. 6172 - 6175 (1991)

Update date:2022-07-30

Topics:

Authors:

Blay, Gonzalo

Cardona, M. Luz

Garcia, Begona

Pedro, Jose R.

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Article abstract of DOI:10.1021/jo00021a040

The short-range functionality transfer from C6 to C8 in eudesmane framework was reported.Santonin (1) was converted into 8-epi-ivangustin (16) and 8-epi-isoivangustin (18) via synthetic pathway involving the aforementioned functionality transfer and treatment of an intermediate diselenide 9 with m-CPBA.

Full text of DOI:10.1021/jo00021a040

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