135501-31-4Relevant articles and documents
Easy and selective method for the synthesis of Mono-, di-, tri-, tetra-O-arylmethyl-p-t-butylcalix[4]arenes
Xie, Yuanyuan,Xia, Wang
experimental part, p. 402 - 406 (2012/09/21)
Mono-, di-, tri- and tetra-O-arylmethyl-p-t-butylcalix[4]arenes were synthesised respectively from p-t-butylcalix[4]arene and arylmethyl bromide through an easy and selective one-step reaction. Mono- and di-arylmethyl ethers of p-t-butylcalix[4]arenes wer
An Easy Access to Tetra-O-Alkylated Calixarenes of Cone Conformation
Bitter, Istvan,Gruen, Alajos,Agai, Bela,Toeke, Laszlo
, p. 7835 - 7840 (2007/10/02)
Fully O-alkylated calixarenes have been synthesized by the alkylation of p-tert-butylcalixarene and its 1,3-dialkylated derivatives in liquid-liquid phase-transfer catalytic process. 1H4 and 1H2R2 could effeciently be deprotonated by aqueous NaOH (5
Calixarenes. 25. Conformations and Structures of the Products of Arylmethylation of Calixarenes
Gutsche, C. David,Reddy, P. Amruta
, p. 4783 - 4791 (2007/10/02)
The arylmethylations of calixarenes reported in this paper serve as companion pieces to an earlier study of the effects of reaction conditions and the structure of the derivatizing agent on the conformational outcome of the aroylation of calixarenes.In contrast to the aroylation reaction, where a significant and predictable relation is observed between the para substituent of the aroyl chloride and the ratio of conformers formed, the arylmethylation reaction shows only a small and much less easily predictable dependence of the conformer ratio on the para substituent of the arylmethyl halide.Also, whereas the products of aroylation are the cone and/or 1,3-alternate conformers, those of arylmethylation are the cone and/or partial cone conformers.While no rationale has yet emerged to explain this difference, a study of the benzylation of dibenzyl and tribenzyl ethers of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrahydroxycalixarene has established that the conformations of the tetraethers are not completely established until the third step in some cases and the fourth step in others.