1355019-45-2Relevant academic research and scientific papers
Heteroarylation of azine N-oxides
Gosselin, Francis,Savage, Scott J.,Blaquiere, Nicole,Staben, Steven T.
, p. 862 - 865 (2012)
Azine N-oxides undergo highly regioselective metalation with TMPZnCl·LiCl under mild conditions. A palladium-catalyzed Negishi cross-coupling reaction of the resulting organozinc species with heteroaromatic bromides provides heterobiaryls specifically oxidized at one nitrogen position in up to 95% yield.
