13555-18-5

Basic information

• Product Name: 1-bicyclo[3.1.0]hex-6-yl-ethanone
• CAS NO: 13555-18-5
• Molecular Weight: 124.183
• Mol File: 13555-18-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bicyclo[3.1.0]hex-6-yl-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bicyclo[3.1.0]hex-6-yl-ethanone(13555-18-5)
• EPA Substance Registry System: 1-bicyclo[3.1.0]hex-6-yl-ethanone(13555-18-5)

Safety Data

• Hazardous Substances Data: 13555-18-5(Hazardous Substances Data)

Upstream product

• 2684-62-0 diazoacetone 
• 142-29-0 cyclopentene 
• 67957-92-0 endo-(Trimethylsilyl)cyclopropane 
• 75-36-5 acetyl chloride 

Downstream Products

• 16650-37-6 bicyclo[3.1.0]hexane-6-carboxylic acid 

Relevant articles and documents

Acetylation de trimethylsilyl bicyclo(n,1,0)alcanes : nouvelles syntheses de l'acetyl cyclohexene-2 et d'acetyl bicyclo(n,1,0)alcanes

Acetylation of trimethylsilyl bicyclo(n,1,0)alkanes was studied using the CH3COCl/AlCl3 complex.The results showed that both larger cycle size (n = 3, 4 or 6) and stereochemistry of the substrate (SiMe3 group in endo or exo position) played a prominent role in the orientation of the reaction : depending upon the starting products, either bicyclic or ethylenic and/or chloro ketones were formed.The results can be rationalized in terms of steric hindrance considerations.They allowed us to propose a new convenient synthesis of acetyl bicyclo(n,1,0)alkanes and also of 1-acetyl 2-cyclohexene.