135557-99-2

Upstream product

• 16934-92-2 (R_p)-menthyl methylphenylphosphinate 
• 16934-93-3 (S_p)-Menthylmethylphenylphosphinate 
• 135441-91-7 ethylene bis-[(R_P)-(-)-menthyl phenylphosphinate] 
• 74-88-4 methyl iodide 
• 89438-78-8 (-)-(S_P)-methylphenylvinylphosphine oxide 
• 891848-03-6 (Sp)-methyl(phenylphosphine oxide) 
• 19315-13-0 methyl(phenyl)phosphineoxide 
• 75502-86-2 C₂₂H₃₈O₂P₂Si₂⁽²⁺⁾*2I^(1-) 

Relevant academic research and scientific papers

STEREOSPECIFIC REDUCTION OF DIASTEREOMERICALLY PURE MENTHYL PHOSPHINATES: A NEW ROUTE TO OPTICALLY ACTIVE PHOSPHINE OXIDES

Diastereomerically pure menthyl phosphinates are stereospecifically reduced by lithium 4,4'-di-tert-butylbiphenylide.Subsequent treatment with alkyl halides affords phosphine oxides with high optical purity.

DETERMINATION OF THE ABSOLUTE CONFIGURATIONS OF 1,2-DIPHOSPHINYLETHENES POSSESSING TWO NONEQUIVALENT ASYMMETRIC PHOSPHORUS CENTRES. CRYSTAL STRUCTURE OF (R,S)-1-(tert-BUTYLPHENYLPHOSPHINYL)-2-(METHYL-PHENYLPHOSPHINYL)ETHANE.

Using signle-crystal X-ray diffraction technique the R,S configuration has been assigned to a homochiral (-)-1-tert-butylphenylphosphinyl-2-methhylphenylphosphinylethane.This has allowed the assignment of absolute configuration also to its P1-epimer as we

OPTICALLY ACTIVE PHOSPHINE OXIDES. 4. A STRAIGHTFORWARD SYNTHESIS OF P-CHIRAL 1,2-DIPHOSPHINOYLETHANES.

The title compounds possesing either one or two homochiral phosphorus centres are conveniently prepared via non-catalyzed addition of secondary phosphine oxides to an optically active vinyl phosphine oxide.