135559-92-1

Basic information

• Product Name: Caranon-4/Isocaranon-4
• Synonyms: Caranon-4/Isocaranon-4
• CAS NO: 135559-92-1
• Molecular Weight: 152.236
• Mol File: 135559-92-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Caranon-4/Isocaranon-4(CAS DataBase Reference)
• NIST Chemistry Reference: Caranon-4/Isocaranon-4(135559-92-1)
• EPA Substance Registry System: Caranon-4/Isocaranon-4(135559-92-1)

Safety Data

• Hazardous Substances Data: 135559-92-1(Hazardous Substances Data)

Upstream product

• 1779-49-3 Methyltriphenylphosphonium bromide 
• 4176-01-6 cis-carane-4-one 
• 936-91-4 α-3,4-Epoxycarane 
• 13466-78-9 3-carene 
• 4017-88-3 (+/-)-cis-caran-trans-4-ol 
• 4017-88-3 cis-carane-4-ol 
• 10395-49-0 (1S,4R,6R)-4-Methoxy-4,7,7-trimethyl-bicyclo[4.1.0]heptan-3-one 
• 10395-49-0 (1S,4S,6R)-4-Methoxy-4,7,7-trimethyl-bicyclo[4.1.0]heptan-3-one 
• 64-17-5 ethanol 
• 498-15-7 (+)-Δ³-carene 

Downstream Products

• 4176-01-6 trans-4-caranone 
• 29172-41-6 2,2-dimethyl-3-(2-methylprop-1-enyl)-cis-1-acetoxymethylcyclopropane 
• 26771-11-9 (1R)-cis-chrysanthemic acid 

Relevant articles and documents

Liquid-phase noncatalytic oxidation of monoterpenoids with nitrous oxide

A series of monoterpenoids differing in the number of double bonds and the pattern of their substitution were tested in the liquid-phase noncatalytic oxidation with nitrous oxide (N2O). The structure of olefins has a significant effect on the oxidation route. In the case of terpenoids containing 1,1-disubstituted double bond, nor-carbonyl compounds are formed with high selectivity.

Transformations of 3-carene oxide at rhenium-containing catalysts

The transformations of 3-carene oxide at rhenium-containing catalysts were studied.The introduction of rhenium into the catalytic system significantly increases the reaction rate and leads to the formation of compounds not previously encountered in the products from the isomerization of 3-carene oxide, i.e., 3-carene, 3(10),4-caradiene, 3,3,6-trimethylcycloheptanone, and 3-caren-10-ol.

SYNTHESIS OF 2,5,5-TRIMETHYLCYCLOHEPTANONE

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