135580-45-9Relevant academic research and scientific papers
Synthese de germyl perfluoroalcanes sulfonates. Quelques aspects de leur reactivite en tant qu'agent de germylation
Castany,Lavayssiere,Dousse
, p. 781 - 801 (1998)
Trifluoromethanesulfonates of germanium(IV) and (II) have been synthesized by reacting triflic acid or silver triflate with several functional organogermanes. Their characterization by 1H, 13C, 19F NMR, IR and mass spectrometry is described. The reactivity with neutral or charged nucleophiles (protic and aprotic) has also been studied. In the case of neutral nucleophiles, the reaction appeared to be a good method for germylation of enolizable ketones and esters.
Zur Synthese neuartiger Triflate der 14. Gruppe
Uhlig, W.
, p. 377 - 383 (2007/10/02)
Trifluoromethanesulfonates of silicon, germanium, tin and lead are obtained by cleavage of the corresponding phenyl derivatives with CF3SO3H.Selective cleavage of the tin-carbon bond is observed in the case of silyl- and germylstannanes.Reaction of bis(trifluoromethanesulfonates) with lithiumorganic compounds leads to functional substituted triflate derivatives.
