Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 781 - 801 (1998)
Update date:2022-08-04
Topics:
Castany
Lavayssiere
Dousse
Trifluoromethanesulfonates of germanium(IV) and (II) have been synthesized by reacting triflic acid or silver triflate with several functional organogermanes. Their characterization by 1H, 13C, 19F NMR, IR and mass spectrometry is described. The reactivity with neutral or charged nucleophiles (protic and aprotic) has also been studied. In the case of neutral nucleophiles, the reaction appeared to be a good method for germylation of enolizable ketones and esters.
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