135594-41-1

Upstream product

• 938-18-1 mesitylene-2-carboxylic acid chloride 
• 124-38-9 carbon dioxide 
• 920-46-7 Methacryloyl chloride 
• 108-67-8 1,3,5-trimethyl-benzene 
• 50-00-0 formaldehyd 
• 2040-15-5 2',4',6'-trimethylpropiophenone 

Downstream Products

• 135594-46-6 2,4-Dimethyl-1-(2,4,6-trimethyl-phenyl)-hex-5-en-1-one 
• 135594-47-7 4-Ethyl-2-methyl-1-(2,4,6-trimethyl-phenyl)-hex-5-en-1-one 
• 135594-45-5 2-Methyl-1-(2,4,6-trimethyl-phenyl)-hex-5-en-1-one 

Relevant academic research and scientific papers

Transition-Metal-Free Reductive Deoxygenative Olefination with CO2

A new transition-metal-free reductive deoxygenative olefination of phosphorus ylides with CO2, an abundant and sustainable C1 chemical feedstock, is described. This catalytic CO2 fixation afforded β-unsubstituted acrylates and vinyl ketones in good yields with broad scope and good functional group tolerance under mild reaction conditions. Cost-effective and easily handled polymethylhydrosiloxane was used as a reductant. Bis(silyl)acetal was proved to be the key intermediate in this reductive functionalization of CO2.

Addition conjuguee d'organometalliques sur des mesitylcetones α-ethyleniques

Reactions of α-ethylenic mesitylketones with a series of organometallic compounds including allylic orgnometallics and organolithium compounds proceed via exclusive conjugated additions as a result of the steric congestion of the carbonyl of these ketones