1355962-48-9Relevant academic research and scientific papers
Unusual thermal reactivity of [W(≡CPh)(NCMe) (I·2-C60)(I·5-C 5Ph5)] in chlorobenzene involving activation of all ligands
Yeh, Wen-Yann
, p. 12046 - 12049 (2012/01/17)
A tung(sten) twister: Heating 1 in chlorobenzene affords 2, 3, C 6Ph6, and C60, and involves C-H bond activation and C-C bond formation of the ligands, as well as chlorine atom abstraction from the solvent. C6Ph6 is presumably generated from insertion of the benzylidyne ligand into the C5Ph5 ring. Compound 3 is an air-stable, 17-electron species, with the phenyldichloromethyl ligand having a unique I·3-allyl-type bonding motif. Copyright
