1355989-27-3Relevant academic research and scientific papers
Total Synthesis of Huperzine Q
Tanimura, Shun,Yokoshima, Satoshi,Fukuyama, Tohru
, p. 3684 - 3686 (2017)
The total synthesis of huperzine Q was accomplished. The synthesis features the construction of the cis-hydrindane skeleton via a Diels-Alder reaction and a ring contraction reaction of an epoxyketone.
DABO Boronate Promoted Conjugate Allylation of α,β-Unsaturated Aldehydes Using Copper(II) Catalysis
Roest, Pjotr C.,Michel, Nicholas W. M.,Batey, Robert A.
, p. 6774 - 6778 (2016/08/16)
The first catalytic method for the selective 1,4-conjugate allylation of α,β-unsaturated aldehydes is reported. The method employs an air-stable diethanolamine-complexed boronic acid (DABO boronate) as the allyl transfer reagent and promotes conjugate add
Rh(I)-catalyzed [5 + 1] cycloaddition of vinylcyclopropanes and CO for the synthesis of α,β- and β,γ-cyclohexenones
Jiang, Guo-Jie,Fu, Xu-Fei,Li, Qian,Yu, Zhi-Xiang
supporting information; experimental part, p. 692 - 695 (2012/03/26)
A cationic Rh(I)-catalyzed [5 + 1] cycloaddition of vinylcyclopropanes and CO has been developed, affording either β,γ-cyclohexenones as major products or α,β-cyclohexenones exclusively, under different reaction conditions.
