1356347-91-5Relevant academic research and scientific papers
C-S bond cleavage during reactions between N,N- diethylthiocarbamoyliminothianes and [MOCl4]- complexes (M = Re, Tc)
Hauenstein, Dirk,Hagenbach, Adelheid,Abram, Ulrich
, p. 1889 - 1894 (2011)
[MOCl4]- complexes (M = Re, Tc) react with thianes derived from N-[(diethylamino)(thiocarbonyl)]benzamidoyl chloride and 2-mercaptophenol (HL1) and 2-mercaptoaniline (HL2) under C-S bond cleavage and formation of oxorhenium(V) and oxotechnetium(V) complexes with the resulting decomposition products 2-mercaptophenol and N-[(dialkylamino)thiocarbonyl]-N′-2-mercaptophenyl)benzamidine (H 2L2a), respectively. The products, (NBu 4)[ReO(S,O-C6H4)2], [ReOCl(L 2a)] and [TcO(L2a)] were obtained in good yields and isolated in crystalline form. Single-crystal X-ray studies reveal square-pyramidal coordination environments with apical oxo ligands for all three product complexes under study. Copyright
