135638-66-3Relevant academic research and scientific papers
Stereoselective synthesis of α-amino and α-thio β-lactones by conjugate addition of amine and thiol nucleophiles to α-methylene β-lactones and their decarboxylation to allylamines and sulfides
Adam,Nava-Salgado
, p. 578 - 584 (1995)
The stereoselective, conjugate addition of secondary, cyclic amines (pyrrolidine and piperidine) and mercaptans (thiophenol, isopropyl, and benzyl thiols and β-mercaptoethanol) to α-methylene β-lactones 1 and 2 was investigated. The corresponding α-(amino
α-Methylene β-Lactones as Masked Allenes and Allene Equivalents: Some Selected Chemical Transformations
Adam, Waldemar,Albert, Rainer,Hasemann, Ludwig,Nava Salgado, Victor O.,Nestler, Bernd,et al.
, p. 5782 - 5785 (2007/10/02)
Selective chemical transformations have been performed on a number of α-methylene β-lactones to illustrate that these highly functionalized heterocycles serve as useful building blocks in organic synthesis.Thus, thermal decarboxylation of these "masked al
