135639-22-4Relevant academic research and scientific papers
Divergent reactivity of phenol- and anisole-tethered donor-acceptor α-diazoketones
Clarke, Aimee K.,Unsworth, William P.,Taylor, Richard J.K.
, p. 5374 - 5382 (2018/03/29)
The first study of the divergent reactivity of phenol/anisole-tethered donor-acceptor α-diazoketones is described. Four distinct product classes were shown to be accessible from closely related α-diazoketone precursors, with the reaction outcome dependent
Spiro-Fused 2,5-Cyclohexadienones from Thermal 1,3-Shifts in Quinol Vinyl Ethers. Reactions in Nonbenzenoid Systems and Limitations of the Chemistry
Swenton, John S.,Bradin, David,Gates, Bradley D.
, p. 6156 - 6163 (2007/10/02)
Addition of functionalized organolithium compounds to quinone monoketals furnished 4-hydroxy-2,5-cyclohexadienone derivatives.The 4-hydroxyl group of these molecules was then transformed into a vinyl ether, and the thermal -shift chemistry of these f
