135654-49-8

Basic information

• Product Name: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate
• Synonyms: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate
• CAS NO: 135654-49-8
• Molecular Weight: 418.381
• Mol File: 135654-49-8.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate(135654-49-8)
• EPA Substance Registry System: diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate(135654-49-8)

Safety Data

• Hazardous Substances Data: 135654-49-8(Hazardous Substances Data)

Upstream product

• 139-66-2 diphenyl sulfide 
• 6226-25-1 2,2,2-trifluoroethyl trifluoromethanesulphonate 
• 100422-07-9 2,2,2-trifluoroethyl(phenyl)iodonium trifluoromethanesulfonate 

Relevant articles and documents

Corey-Chaykovsky Reactions of Nitro Styrenes Enable cis-Configured Trifluoromethyl Cyclopropanes

Trifluoromethyl-substituted cyclopropanes are an attractive family of building blocks for the construction of pharmaceutical and agrochemical agents. This work demonstrated the utilization of fluorinated sulfur ylides as versatile reagents for Corey-Chaykovsky cyclopropanation reactions of nitro styrenes. This protocol favored the synthesis of cis-configured trifluoromethyl cyclopropanes for a broad range of substrates with excellent yields and good diastereoselectivities.

Diastereoselective Synthesis of CF3-Containing Vicinal Diamines

The highly diastereoselective synthesis of CF3-containing vicinal diamines by a convenient two-step procedure without the need to isolate the intermediate products is described.

PESTICIDALLY ACTIVE DIAZINE-AMIDE COMPOUNDS

Compounds of formula I (Formula I) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.

PESTICIDALLY ACTIVE DIAZINE-AMIDE COMPOUNDS

Compounds of formula I (l) wherein the substituents are as defined in claim 1, and the agrochemically acceptable salts, stereoisomers, enantiomers, tautomers and N-oxides of those compounds, can be used as insecticides.