135679-72-0Relevant academic research and scientific papers
Cationic dirhodium carboxylate-catalyzed synthesis of dihydropyrimidones from propargyl ureas
Yang, Miao,Odelberg, Shannon J.,Tong, Zongzhong,Li, Dean Y.,Looper, Ryan E.
supporting information, p. 5744 - 5750 (2013/06/27)
Cationic Rh(II) complexes are able to catalyze the regioselective hydroamination of propargyl ureas in a 6-endo fashion. This transformation permits access to interesting substitution patterns of dihydropyrimidines, which have found use as nucleotide exch
Highly selective TFAA-cleavage of tertiary 2,4-dimethoxybenzylamines and its use in the synthesis of secondary amines
Nussbaumer,Baumann,Dechat,Harasek
, p. 4591 - 4602 (2007/10/02)
TFAA-treatment of allylic, propargylic, homopropargylic and some benzylic tert. 2, 4-dimethoxybenzylamines leads to highly selective cleavage of their dimethoxybenzylic C-N bonds. The resultant trifluoroacetamides can then readily be converted to the corresponding secondary amines.
