1356826-20-4

Basic information

• Product Name: PdCl(C₆H₄(NCH₂CH₂N(C₂H₅)2)NNC₆H₄Cl)
• CAS NO: 1356826-20-4
• Molecular Weight: 471.725
• Mol File: 1356826-20-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: PdCl(C₆H₄(NCH₂CH₂N(C₂H₅)2)NNC₆H₄Cl)(CAS DataBase Reference)
• NIST Chemistry Reference: PdCl(C₆H₄(NCH₂CH₂N(C₂H₅)2)NNC₆H₄Cl)(1356826-20-4)
• EPA Substance Registry System: PdCl(C₆H₄(NCH₂CH₂N(C₂H₅)2)NNC₆H₄Cl)(1356826-20-4)

Safety Data

• Hazardous Substances Data: 1356826-20-4(Hazardous Substances Data)

Upstream product

• 1356826-23-7 C₆H₄(NHCH₂CH₂N(C₂H₅)2)NNC₆H₄Cl 

Relevant articles and documents

Synthesis, characterization and structure of new diazoketiminato chelates of palladium(II): Potential catalyst for C-C coupling reactions

The 1N-(N,N-diethylaminoethyl)-2-arylazoaniline, HL [where HL = ArN = NC6H4N(H){C2H4N(C2H 5)2}; Ar = C6H5 (for HL 1), p-MeC6H4 (for HL2) or p-ClC 6H4 (for HL3)], ligands were prepared by treating the appropriate 2-(arylazo)aniline with 2-bromo-N,N-diethylethanamine. Reactions of Na2PdCl4 with HL afforded the [(L)PdCl] complexes. HL binds palladium(II) in a tridentate fashion (N,N,N), forming a new diazoketiminato chelate. The X-ray structure of [(L3)PdCl] was determined to confirm the characterization. The newly synthesized complex [(L1)PdCl] was utilized to carry out Suzuki and Heck reactions for a variety of substrates.