1357569-99-3

Upstream product

• 514214-80-3 [(S)-2-methyl-1-((S)-1-phenyl-ethylcarbamoyl)-propyl]-carbamic acid tert-butyl ester 
• 147649-95-4 (S)-2-Methyl-4-pentenoic acid phenylmethyl ester 
• 152441-67-3 benzyl (S)-2-methyl-4-oxabutanoate 
• 3886-69-9 (R)-1-phenyl-ethyl-amine 
• 13734-41-3 t-Boc-L-valine 
• 1357570-06-9 C₂₆H₃₆F₃N₃O₅ 
• 1357570-05-8 C₂₃H₃₅N₃O₄ 
• 1357569-96-0 (2S)-4-acetoxy-5,5,5-trifluoro-2-methylpentanoic acid 
• 1357569-95-9 benzyl (2S)-4-acetoxy-5,5,5-trifluoro-2-methylpentanoate 

Relevant academic research and scientific papers

A peptide-embedded trifluoromethyl ketone catalyst for enantioselective epoxidation

The development of peptide-based oxidation catalysts that use a transiently generated dioxirane as the chemically active species is reported. The active catalyst is a chiral trifluoromethyl ketone (Tfk) with a pendant carboxylic acid that can be readily incorporated into a peptide. These peptides were capable of epoxidizing alkenes in high yield (up to 89%) and enantiomeric ratios (er) ranging from 69.0:31.0 to 91.0:9.0, depending on the alkene substitution pattern.