135888-07-2Relevant academic research and scientific papers
1,1,3,3-Tetraethyl-1,3-disilaisoindolines; Chromatographically Stable Silicon-Based Protection for Primary Amines
Davis, Anthony P.,Gallagher, Patrick J.
, p. 3269 - 3272 (1995)
The title compounds 4 have potential as protected derivatives of primary aliphatic amines.They are more stable to acid than the corresponding Stabase and Benzostabase derivatives 2 and 3, and are stable to flash chromatography on silica gel using all but the least polar solvent systems.
A Strained Disilane-Promoted Carboxylation of Organic Halides with CO2 under Transition-Metal-Free Conditions
Mita, Tsuyoshi,Suga, Kenta,Sato, Kaori,Sato, Yoshihiro
supporting information, p. 5276 - 5279 (2015/11/18)
By using a strained four-membered ring disilane (3,4-benzo-1,1,2,2-tetraethyldisilacyclobutene) and CsF, a wide range of aryl, alkenyl, alkynyl, benzyl, allyl, and alkyl halides was successfully carboxylated under an ambient CO2 atmosphere (CO2 balloon) at room temperature within 2 h. In this carboxylation, a highly reactive silyl anion, which is generated from the disilane and CsF, is a key to facilitating the formation of a carbanion equivalent. The resulting anionic species can be trapped with CO2 to produce carboxylic acids with high efficiency.
Steric and Electronic Effects in Cyclic Alkoxyamines - Synthesis and Applications as Regulators for Controlled/Living Radical Polymerization
Wetter, Christian,Gierlich, Johannes,Knoop, Christoph Alexander,Mueller, Christoph,Schulte, Tobias,Studer, Armido
, p. 1156 - 1166 (2007/10/03)
The synthesis of new six- and seven-membered cyclic alkoxyamines bearing ethyl groups at the α-N position of the alkoxyamines is described. The key step in the synthesis of the sterically hindered six-membered cyclic alkoxyamines is a Wadsworth-Horner-Emm
