1358883-29-0Relevant academic research and scientific papers
Heck coupling in the gas phase: Examination of the reaction mechanism by ion/molecule reactions and mass spectrometry
Fiebig, Lukas,Schmalz, Hans-Guenther,Schaefer, Mathias
experimental part, p. 307 - 310 (2012/05/05)
The Heck reaction of isoprene with (p-iodophenyl)-trimethylammonium iodide was conducted in the gas phase. Relevant species of the catalytic cycle including the ionic product of the Pd-catalyzed coupling reaction were reliably characterized by exact ion mass measurements and by characteristic product ions generated by tandem-MS.
