1358895-33-6

Basic information

• Product Name: 5-(tert-butyldimethylsilyloxy)-3-methylene-1-(pentafluorophenyl)pentan-1-ol
• Synonyms: 5-(tert-butyldimethylsilyloxy)-3-methylene-1-(pentafluorophenyl)pentan-1-ol
• CAS NO: 1358895-33-6
• Molecular Weight: 396.473
• Mol File: 1358895-33-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(tert-butyldimethylsilyloxy)-3-methylene-1-(pentafluorophenyl)pentan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(tert-butyldimethylsilyloxy)-3-methylene-1-(pentafluorophenyl)pentan-1-ol(1358895-33-6)
• EPA Substance Registry System: 5-(tert-butyldimethylsilyloxy)-3-methylene-1-(pentafluorophenyl)pentan-1-ol(1358895-33-6)

Safety Data

• Hazardous Substances Data: 1358895-33-6(Hazardous Substances Data)

Upstream product

• 653-37-2 perfluorobenzaldehyde 
• 74915-94-9 1-(tert-butyldimethylsiloxy)-3-methyl-3-butene 

Downstream Products

• 1358895-39-2 3-methylidene-1-(pentafluorophenyl)pentane-1,5-diol 

Relevant articles and documents

Synthesis of perhydrofuro[2,3-b]furans from isopentenyl alcohol through carbonyl-ene and wacker-type reactions

A range of 2-substituted perhydrofuro[2,3-b]furans have been synthesized in a stereoselective manner through a sequence involving the Lewis-acid catalyzed carbonyl-ene reaction of a protected isopentenyl alcohol with a variety of enophiles, deprotection of the corresponding monoprotected diols, and palladium-catalyzed intramolecular acetalization under Wacker-type reaction conditions. A new synthetic approach toward the synthesis of perhydrofuro[2,3-b]furans is described. The strategy is based on the carbonyl-ene reaction for a protected isopentenyl alcohol with several activated enophiles followed by deprotection and palladium-catalyzed intramolecular acetalization. Copyright