135907-86-7Relevant academic research and scientific papers
Triazolopyridines. Part 11. Ylides derived from 2-acylmethyltriazolopyridinium salts
Abarca, Belen,Ballesteros, Rafael,Mojarrad, Fatemeh,Metni, Mohamed R.,Garcia-Granda, Santiago,Perez-Carreno, Enrique,Jones, Gumos
, p. 5277 - 5286 (2007/10/02)
Ylides derived from 2-acylmethyltriazolopyridinium salts (2a) -(2c) react with methyl or ethyl propiolate and with dimethyl acetylenedicarboxylate to give ylides (3a)-(3e), (6) or (7). In some cases 1:2 adducts are formed, shown to be the novel ylides (8a)-(8d); an X-ray diffraction confirms structure (8a).
