13594-33-7Relevant academic research and scientific papers
Synthesis of 2,2-Dialkyl-1-aminocyclopropanecarboxylic Acids from α-Chloro Ketimines
Kimpe, Norbert De,Sulmon, Paul,Brunet, Pascal
, p. 5777 - 5784 (2007/10/02)
2,2-Dialkyl-1-aminocyclopropanecarboxylic acids, abbreviated as 2,2-dialkyl Acc's, are potential plant growth regulators which were synthesized by ring closure of α-chloro imines.The synthetic scheme leading to these Acc analogues entails a newly developed regiospecific synthesis of tertiary α-chloro ketimines, the trapping with cyanide of a transient Favorskii derived cyclopropylideneamine, and the hydrolytic conversion of 1-(N-tert-butylamino)-2,2-dialkylcyclopropanecarbonitriles into the title compounds.
SYNTHESIS OF 2,2-DIALKYL-1-AMINOCYCLOPROPANECARBOXYLIC ACIDS FROM Α-CHLOROIMINES
De Kimpe, Norbert,Sulmon, Paul,Brunet, Pascal,Lambein, Fernand,Schamp, Niceas
, p. 1863 - 1866 (2007/10/02)
2,2-Dialkyl-ACC analogues, i.e. potential plant growth regulators, were synthesized via straightforward cyclopropanation of α-chloroimines.
