135958-12-2Relevant academic research and scientific papers
Dearylation of arylphosphine oxides using a sodium hydride-iodide composite
Tejo, Ciputra,Pang, Jia Hao,Ong, Derek Yiren,Oi, Miku,Uchiyama, Masanobu,Takita, Ryo,Chiba, Shunsuke
supporting information, p. 1782 - 1785 (2018/02/21)
A new protocol for the dearylation of arylphosphine oxides was developed using sodium hydride (NaH) in the presence of lithium iodide (LiI). The transient sodium phosphinite could be functionalized with a range of electrophiles in a one-pot fashion.
Radical addition to vinylphosphine oxides: 1,2-stereoinduction of phosphorus stercogcnic centre
Brandi, Alberto,Cicchi, Stefano,Goti, Andrea,Pietrusiewiez, K. Michal
, p. 3265 - 3268 (2007/10/02)
Carbon cantered radicals derived from reactions of halides 3-5 with Bu3SnH in the presence of AIBN havebeentrapped by diphenylvinylphosphine oxide 2 giving the addition products 6-8 in high yields. Free radical addition to 2 employing the Barto
