13596-41-3

Basic information

• Product Name: 2,2,4,4,6,6,8,8,10,10-decachloro-1,3,5,7,9,2lambda~5~,4lambda~5~,6lambda~5~,8lambda~5~,10lambda~5~-pentazapentaphosphecine
• CAS NO: 13596-41-3
• Molecular Formula: Cl₁₀N₅P₅
• Molecular Weight: 579.4323
• Mol File: 13596-41-3.mol
• Article Data: 3

Chemical Properties

• Density: 2.59g/cm³
• Refractive Index: 1.801
• CAS DataBase Reference: 2,2,4,4,6,6,8,8,10,10-decachloro-1,3,5,7,9,2lambda~5~,4lambda~5~,6lambda~5~,8lambda~5~,10lambda~5~-pentazapentaphosphecine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2,4,4,6,6,8,8,10,10-decachloro-1,3,5,7,9,2lambda~5~,4lambda~5~,6lambda~5~,8lambda~5~,10lambda~5~-pentazapentaphosphecine(13596-41-3)
• EPA Substance Registry System: 2,2,4,4,6,6,8,8,10,10-decachloro-1,3,5,7,9,2lambda~5~,4lambda~5~,6lambda~5~,8lambda~5~,10lambda~5~-pentazapentaphosphecine(13596-41-3)

Safety Data

• Hazardous Substances Data: 13596-41-3(Hazardous Substances Data)

Upstream product

• 1586-73-8 tris(trimethylsilyl)amine 
• 10026-13-8 phosphorus pentachloride 
• 12125-02-9 ammonium chloride 

Downstream Products

• 1184-10-7 2,2,4,4,6,6-hexaphenoxycyclotriphosphazene 
• 992-79-0 1,1,3,3,5,5,7,7-octaphenoxycyclotetraphosphazatetraene 
• 19258-92-5 decafluoropentaphosphazene 

Relevant articles and documents

Structure and conformation of the medium-sized chlorophosphazene rings

Medium-sized cyclic oligomeric phosphazenes [PCl2N]m (where m = 5-9) that were prepared from the reaction of PCl5 and NH4Cl in refluxing chlorobenzene have been isolated by a combination of sublimation/extraction and column chromatography from the predominant products [PCl2N]3 and [PCl2N]4. The medium-sized rings [PCl2N]m have been characterized by electrospray ionization-mass spectroscopy (ESI-MS), their 31P chemical shifts have been reassigned, and their T1 relaxation times have been obtained. Crystallographic data has been recollected for [PCl 2N]5, and the crystal structures of [PCl 2N]6, and [PCl2N]8 are reported. Halogen-bonding interactions were observed in all the crystal structures of cyclic [PCl2N]m (m = 3-5, 6, 8). The crystal structures of [P(OPh)2N]7 and [P(OPh)2N]8, which are derivatives of the respective [PCl2N]m, are also reported. Comparisons of the intermolecular forces and torsion angles of [PCl2N]8 and [P(OPh)2N]8 with those of three other octameric rings are described. The comparisons show that chlorophosphazenes should not be considered prototypical, in terms of solid-state structure, because of the strong influence of halogen bonding.

A new route to the phosphazene polymerization precursors, Cl3P=NSiMe3 and (NPCl2)3

An improved synthesis of the phosphazene polymerization precursors, hexachlorocyclotriphosphazene, (NPCl2)3 (1), and Cl3P=NSiMe3 (2) is reported. The addition of PCl5 to N(SiMe3)3 in methylene chloride at 40 °C produced a mixture of phosphazenes which contained 76% of 1. However, the addition of N(SiMe3)3 to PCl5 in methylene chloride at 0 °C, followed by the addition of hexane, provided 2 in 40% yield. The mechanism of the reaction is discussed.