992-79-0Relevant articles and documents
Synthesis of a dendrimeric phenoxy-substituted cyclotetraphosphazene and its non-covalent interactions with multiwalled carbon nanotubes
Okutan, Elif,?o?ut, Bünyemin,Beyaz Kayiran, Saadet,Durmu?, Mahmut,Kili?, Adem,Ye?ilot, Serkan
, p. 344 - 350 (2014)
A dendrimeric phenoxy-substituted cyclotetraphosphazene has been prepared for the non-covalent functionalization of multiwalled carbon nanotubes (MWCNTs). The synthesized cyclotetraphosphazene derivatives (2-4) and dendrimeric cyclotetraphosphazene (5) have been characterized by standard spectroscopic techniques. The functionalization of MWCNTs with compound 5 has been accomplished and the resulting MWCNT-5 hybrid has been characterized by 31P NMR, 1H NMR, Raman spectroscopy, X-ray diffraction (XRD), energy dispersive X-ray (EDX), fluorescence, thermal gravimetric analysis (TGA) and high-resolution transmission electron microscopy (HRTEM) techniques. The results showed that the dendrimeric compound 5 has been attached to the MWCNTs via non-covalent π-π interactions between the phenoxy groups on the dendrimeric compound 5 and the extended π system of the MWCNTs. The MWCNT-5 hybrid exhibited significant dispersion stability in common organic solvents.
CYCLIC PHOSPHAZENES, PROCESS FOR PREPARING THEM, FLAME RETARDANTS CONTAINING THE SAME AS THE ACTIVE INGREDIENT, AND RESIN COMPOSITIONS AND MOLDED ARTICLES CONTAINING THE FLAME RETARDANTS
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Page 19, (2008/06/13)
The present invention relates to cyclic phosphazenes of general formula (1) wherein Q is a halogen and/or an aryloxy group, and m is an integer of 3 to 10, which are characterized by being substantially free from linear phosphazenes of general formula (2) wherein Q is a halogen and/or an aryloxy group, and n is an integer of 1 to 20 and by having an extremely low content of halogen, and which are appropriate to flame retardants for resins; processes for preparing the same; flame retardants containing the same as an active ingredient; resin compositions containing the cyclic phosphazenes; and molded articles therefrom.