1359859-45-2Relevant articles and documents
Visible-light-mediated utilization of α-aminoalkyl radicals: Addition to electron-deficient alkenes using photoredox catalysts
Miyake, Yoshihiro,Nakajima, Kazunari,Nishibayashi, Yoshiaki
supporting information; experimental part, p. 3338 - 3341 (2012/04/10)
Synthetic use of α-aminoalkyl radicals formed by single electron oxidation of amines is quite limited. Here we demonstrate addition of α-aminoalkyl radicals to electron-deficient alkenes by visible-light-mediated electron transfer using transition metal polypyridyl complexes as photocatalysts, via a sequential redox pathway.