135987-22-3Relevant academic research and scientific papers
Indium in organic synthesis: Convenient synthesis of β,γ-unsaturated ketones
Yadav,Srinivas, Dale,Reddy, Gondi Sudershan,Bindu, Konuru Hima
, p. 8745 - 8748 (1997)
A mild and efficient method for the preparation of β,γ unsaturated ketones by a simple reaction on acid chloride with allyl, crotyl, prenyl bromide and indium in DMF is described.
Synthesis of allyl ketone via Lewis acid promoted Barbier-type reaction
Lee,Lin
, p. 8803 - 8806 (2007/10/03)
A series of allyl ketones were synthesized from the mixture of zinc, nitrile and allyl bromide in the presence of AlCl3 via Barbier-type reaction condition. When crotyl bromide was used for the allylation, only the γ-adduct was produced via the
Carbon-carbon bond forming reactions of η3-allyl iron tricarbonyl anions with carbon electrophiles
Chang, Seok,Yoon, Jaeyon,Brookbart, Maurice
, p. 1869 - 1879 (2007/10/02)
Reaction of the η3-allyl iron tricarbonyl anion, 1, with alkyl halides (RX, R = -CH3, -CH2Ph, -(CH2)3CH3, -CH(CH3)2,-CH2CH=CH2) followed by treat
A Practical Synthesis of Rosefuran. Furans from Acetylenes and Allyl Alcohols
Trost, Barry M.,Flygare, John A.
, p. 1078 - 1082 (2007/10/02)
A new atom-economical synthetic strategy for the synthesis of furans emerges from β,γ-unsaturated ketones which are readily available from acetylenes and allyl alcohols by simple additions in the presence of a ruthenium catalyst.Dihydroxylation using cata
Allylation of Aldehydes by Allyl- and Crotyltributyltin in the Presence zof Catalytic Amounts of Bu2SnCl2 Complex
Yano, Katsunori,Baba, Akio,Matsuda, Haruo
, p. 66 - 70 (2007/10/02)
In nearly neutral media, the reaction of allylic tributyltin with aldehydes is effectively catalyzed by Bu2SnCl2 complexes.The addition of coordinative reagents and benzoyl chloride as a quencher is required of the catalytic allylation, furnishing homoall
Allylation of Acid Chlorides by Allyltributyltin in the Presence of Catalytic Amounts of Dibutyltin Dichloride
Yano, Katsunori,Baba, Akio,Matsuda, Haruo
, p. 1181 - 1184 (2007/10/02)
Redistribution of allyltributyltin and dibutyltin dichloride into allyldibutyltin chloride and tributyltin chloride is enhanced by coordinative compounds such as phosphine oxide and ammonium chloride.This redistribution is applied to the reaction of allyl
