13599-69-4

Basic information

• Product Name: N-Methylcarbanilic acid phenyl ester
• Synonyms: Methylphenylcarbamic acid phenyl ester;N-Methylcarbanilic acid phenyl ester
• CAS NO: 13599-69-4
• Molecular Formula: C₁₄H₁₃NO₂
• Molecular Weight: 227.2585
• Mol File: 13599-69-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 330.6°Cat760mmHg
• Flash Point: 153.7°C
• Appearance: /
• Density: 1.177g/cm³
• Vapor Pressure: 0.000165mmHg at 25°C
• Refractive Index: 1.609
• CAS DataBase Reference: N-Methylcarbanilic acid phenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-Methylcarbanilic acid phenyl ester(13599-69-4)
• EPA Substance Registry System: N-Methylcarbanilic acid phenyl ester(13599-69-4)

Safety Data

• Hazardous Substances Data: 13599-69-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C14H13NO2/c1-15(12-8-4-2-5-9-12)14(16)17-13-10-6-3-7-11-13/h2-11H,1H3

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 1885-14-9 phenyl chloroformate 
• 3416-49-7 N-butyl-N-methylaniline 
• 100-61-8 N-methylaniline 
• 108-95-2 phenol 
• 4285-42-1 N-phenyl-N-methylcarbamoyl chloride 
• 100-67-4 potassium phenolate 
• 874-52-2 N,N-dimethylaniline N-oxide 
• 92289-43-5 imidazole-1-carboxylic acid methylphenylamide 

Relevant articles and documents

Synthesis of highly condensed heterocycles using radical reactions

Using radical chemistry novel highly condensed heterocycles have been synthesized. The mechanism for their formation is discussed.

Efficient demethylation of N,N-dimethylanilines with phenyl chloroformate in ionic liquids

Demethylation of N,N-dimethylanilines was carried out in various ionic liquids and acetonitrile as well as under solvent-free conditions. We have demonstrated that their reactivity dramatically depends on the ionic liquid employed; [bmim]Cl showed the bes

Mild and selective deprotection of carbamates with Bu4NF

A new mild method allowing the removal of carbamates using TBAF in THF is reported. Reactions were performed on indole, indoline, N-methyl aniline, aniline and tryptamine derivatives. The observed selectivity according to the carbamates or the substrates is discussed. A mechanism is postulated. Graphical Abstract