136001-63-3Relevant academic research and scientific papers
REACTION OF CYCLIC PARTIAL PHOSPHITE ESTERS WITH ENAMINES - AN ELECTROPHILIC FORM OF THE PUDOVIK REACTION
Safina, Yu. G.,Malkova, G. Sh.,Cherkasov, R. A.
, p. 562 - 574 (2007/10/02)
It was established that the ease of noncatalytic addition of cyclic and acyclic partial phosphites to enamines is due to the H-donor capacity of the acids and to the degree of localization of the electron density at the C=C bond in the unsaturated partner.It was shown that cyclic phosphites add initially at the carbon-carbon multiple bond of the conjugated N-C=C-C=O system of enamino ketones with the final formation of bisphosphorylated derivatives.
