136001-85-9Relevant academic research and scientific papers
ANHYDROUS DERIVATIVES OF ACIDS OF TRIVALENT PHOSPHORUS CONTAINING A CYANO GROUP
Pudovik, A. N.,Nazmutdinova, V. N.,Chirkova, L. P.
, p. 551 - 554 (2007/10/02)
Chloro- and O-acetyl cyanides of trivalent phosphorus disproportionate into the corresponding dicyanides and dichlorides or diacyl derivatives of P(III), while S-acetyl cyanothiophosphites and -phosphonites are thermally stable.Alcoholysis of S-acetyl cyanothiophosphite at room temperature is accompanied by the formation of O.O-diethyl S-acetyl thiophosphite.At low temperature, this reaction gives diethyl cyanophosphite.
