136025-93-9

Upstream product

• 2958-89-6 N-(chlorosulfanyl)morpholine 
• 54088-45-8 L(-)mentylphenylhydrogen phosphonate (S) 
• 54088-45-8 Phenyl-phosphinothioic acid O-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl) ester 
• 2216-51-5 (-)-menthol 
• 644-97-3 Dichlorophenylphosphine 
• 110-91-8 morpholine 
• 129992-32-1 R_P-L-menthoxyphenylthioxaphosphoranesulfenyl chloride 
• 161154-81-0 C₂₈H₄₆NOPS₂ 

Downstream Products

• 161154-81-0 C₂₈H₄₆NOPS₂ 
• 136025-92-8 C₃₂H₄₈O₂P₂S₄ 
• 136025-92-8 (S_P,S_P)-bis<(-)menthyloxy(phenyl)thiophosphoryl> disulfide 
• 129992-32-1 R_P-L-menthoxyphenylthioxaphosphoranesulfenyl chloride 

Relevant academic research and scientific papers

P-chiral thioxophosphoranesulfenyl chlorides RR'P(S)SCl. A unique stereochemical probe to study nucleophilic displacement at a dicoordinate sulfur center

A stereospecific synthesis of P-chiral sulfenyl chlorides 6a,b has been developed from P-chiral sulfenylamide 9a,b,c by a novel procedure employing 2Me3SiCl + 2EtOH as the reagent of choice. The sulfenylamides 9a,b,c were prepared either by ste

NEW CHEMISTRY AND STEREOCHEMISTRY OF ORGANOPHOSPHORUS PSEUDOHALOGENS

Synthesis, chemistry and stereochemistry of organophosphorus-sulfur(selenium)pseudohalogens are discussed and rationalized.

Stereospecyfic Synthesis of P-Epimeric (SP,SP)-Bis- Disulphide. An Unusual Case of Steric Selection

Iodine-water oxidation of compound 1, condensation of 1 with (R)P-7 together with the reaction of the latter with trimethylsilyl azide results in the formation of stable (S)P(S)P-2.