13603-60-6

Basic information

• Product Name: Benzeneethanethioic acid, a-oxo-, S-methyl ester
• CAS NO: 13603-60-6
• Molecular Formula: C9H8O2S
• Molecular Weight: 180.227
• Mol File: 13603-60-6.mol

Chemical Properties

• CAS DataBase Reference: Benzeneethanethioic acid, a-oxo-, S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneethanethioic acid, a-oxo-, S-methyl ester(13603-60-6)
• EPA Substance Registry System: Benzeneethanethioic acid, a-oxo-, S-methyl ester(13603-60-6)

Safety Data

• Hazardous Substances Data: 13603-60-6(Hazardous Substances Data)

Upstream product

• 100-47-0 benzonitrile 
• 33577-16-1 methyl methylsulfinylmethyl sulfide 
• 52922-65-3 ω-(Methylthio)-ω-(methylsulfinyl)acetophenone 
• 87228-53-3 2-Methylsulfanyl-1-phenyl-2-(toluene-4-sulfonyl)-ethanone 
• 2813-22-1 2-methanesulfinyl-1-phenyl-ethanone 
• 21504-18-7 2,2,2-Tris-methylsulfanyl-1-phenyl-ethanone 
• 7714-33-2 methyl phenylethynyl sulfide 
• 100-42-5 styrene 
• 67-68-5 dimethyl sulfoxide 
• 536-74-3 phenylacetylene 
• 932-88-7 1-iodo-2-phenylethyne 

Relevant articles and documents

A simple and high yield general route to methyl α-oxo thiolcarboxylates

Methyl α-oxo thiolcarboxylates (aliphatic, aromatic and heteroaromatic) are obtained in good to excellent yields by hydrolysis of the corresponding trimethyl α-oxo trithioorthoesters with N-bromosuccinimide in aqueous THF or with HgO/35% aqueous HBF4

Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2-Dicarbonyls

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Oxidative Thioesterification of Alkenes Mediated by 1,3-Dibromo-5,5-dimethylhydantoin and DMSO for the Synthesis of α-Ketothioesters

A simple and mild approach for the synthesis of α-ketothioesters via 1,3-Dibromo-5,5-dimethylhydantoin (DBH)/DMSO mediated oxidative thioesterification of alkenes has been developed. Various of α-ketothioesters products were produced in moderate to good y

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An unprecedented set of efficient, economical, atom-economic and exceedingly selective I2-DMSO-promoted methods is described for the generation of different structures. The reaction represents the first of its kind, involving the use of different iodine concentrations, temperatures, acids and salt to adjust the selectivity for the synthesis of different alkenes, α-functionalized ketones and α-ketomethylthioesters.

UTILIZATION OF METHYLTHIOMETHYL p-TOLYL SULFONE IN ORGANIC SYNTHESIS

Methylthiomethyl p-tolyl sulfone was found to be one of the useful reagents for preparation of various organic compounds such as S-methyl α-ketocarbothioates, carboxylic esters, five- and six-membered cycloalkanones, and α-methoxy-α-arylacetic esters.