136053-35-5

Upstream product

• 873-73-4 4-n-chlorophenylacetylene 
• 75-77-4 chloro-trimethyl-silane 
• 1066-54-2 trimethylsilylacetylene 
• 31928-44-6 2-bromo-4-chloroiodobenzene 

Downstream Products

• 136002-59-0 4-chloro-2-trimethylsilylphenylacetylene 
• 136053-46-8 5-Chloro-1,3-bis-trimethylsilanyl-2-trimethylsilanylethynyl-benzene 

Relevant academic research and scientific papers

Rhodium-catalyzed tandem cyclization/Si-C activation reaction for the synthesis of siloles

Siloles represent an important emerging class of photoluminescent materials. Reported herein is a new synthetic strategy involving a tandem cyclization/Si-C activation reaction featuring high efficiency, wide substrate scope, and practical utility. This m

Regioselective Synthesis and Polymerization of Substituted o-Trimethylsilylphenylacetylenes

Substituted o-trimethylsilylphenylacetylenes were synthesized by o-metalation of phenylacetylenes with complex reagent of butyllithium and t-BuOK, and were polymerized in the presence of a tungsten catalyst giving deeply colored poly(arylacetylene)s.Relationship between the structure of monomers and polymers was examined.