1360593-30-1Relevant articles and documents
Diastereoselective Synthesis of Dibenzo[b,d]azepines by Pd(II)-Catalyzed [5 + 2] Annulation of o-Arylanilines with Dienes
Bai, Lu,Wang, Yan,Ge, Yicong,Liu, Jingjing,Luan, Xinjun
, p. 1734 - 1737 (2017)
An efficient method for the construction of dibenzo[b,d]azepines containing two distinct stereogenic elements in a highly diastereoselective fashion is described. The key of the [5 + 2] reaction is to form a π-allylpalladium species through sequential C-H