136066-63-2

Upstream product

• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 136066-62-1 (+/-)-3-<2-hydroxy-2-methyl-2-(2,4,6-trimethylphenyl)acetoxy>-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 136066-56-3 (1S,2R,5S,6R)-Tricyclo[4.2.1.0^2,5]non-7-en-3-ol 
• 136066-61-0 3-(2-oxopropionoxy)-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 2633-66-1 2-mesitylmagnesium bromide 

Downstream Products

• 129337-26-4 (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester 
• 129337-26-4 (S)-2-(2,4,6-Trimethyl-phenyl)-2-trimethylsilanyloxy-propionic acid (3aS,4R,7aS)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester 
• 129363-16-2 (S)-2-Hydroxy-2-(2,4,6-trimethyl-phenyl)-propionic acid (3aR,4S,7aR)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester 
• 129363-16-2 (S)-2-Hydroxy-2-(2,4,6-trimethyl-phenyl)-propionic acid (3aS,4R,7aS)-2-ethyl-1,3-dioxo-2,3,3a,4,7,7a-hexahydro-1H-isoindol-4-yl ester 
• 129337-25-3 (+/-)-(E)-1-<2-methyl-2-(2,4,6-trimethylphenyl)-2-<(trimethylsilyl)oxy>acetoxy>-1,3-butadiene 

Relevant academic research and scientific papers

Diene-dienophile hydrogen-bonding control of diels-alder reactions with dienes bearing a remote stereogenic center. Amplification of the receptor nature of dienes by conformational tuning leading to high diastereofacial discrimination

The Diels-Alder reactions of 1-(O-methylmandeloxy)butadiene and its analogues, bearing a remote stereogenic center, have been studied to elucidate the stereoselective control elements. Several model dienes (5a-5f) have been designed to enhance the facial