1360733-85-2Relevant academic research and scientific papers
α-fluoroallenoate synthesis via N-heterocyclic carbene-catalyzed fluorination reaction of alkynals
Wang, Xu,Wu, Zijun,Wang, Jian
, p. 576 - 579 (2016/02/18)
The first catalytic α-fluoroallenoate synthesis is described. With a suitable combination of N-heterocyclic carbene precatalyst, base, and fluorine reagent, the reaction proceeded smoothly to yield a wide range of α-fluoroallenoates with excellent chemose
N -heterocyclic carbene-catalyzed internal redox reaction of alkynals: An efficient synthesis of allenoates
Zhao, Yu-Ming,Tam, Yik,Wang, Yu-Jie,Li, Zigang,Sun, Jianwei
, p. 1398 - 1401 (2012/06/01)
An efficient N-heterocyclic carbene (NHC)-catalyzed internal redox reaction of alkynals that bear a γ leaving group has been developed. This process provides a new access to a range of allenoates in good yields. Preliminary results demonstrate that the en
