1360733-83-0Relevant academic research and scientific papers
Synthesis of Functionalized [3], [4], [5] and [6]Dendralenes through Palladium-Catalyzed Cross-Couplings of Substituted Allenoates
Lippincott, Daniel J.,Linstadt, Roscoe T. H.,Maser, Michael R.,Lipshutz, Bruce H.
supporting information, p. 847 - 850 (2017/01/14)
A mild method for the synthesis of highly functionalized [3]–[6]dendralenes is reported, representing a general strategy to diversely substituted higher homologues of the dendralenes. The methodology utilizes allenoates bearing various substitution patter
α-fluoroallenoate synthesis via N-heterocyclic carbene-catalyzed fluorination reaction of alkynals
Wang, Xu,Wu, Zijun,Wang, Jian
supporting information, p. 576 - 579 (2016/02/18)
The first catalytic α-fluoroallenoate synthesis is described. With a suitable combination of N-heterocyclic carbene precatalyst, base, and fluorine reagent, the reaction proceeded smoothly to yield a wide range of α-fluoroallenoates with excellent chemose
N -heterocyclic carbene-catalyzed internal redox reaction of alkynals: An efficient synthesis of allenoates
Zhao, Yu-Ming,Tam, Yik,Wang, Yu-Jie,Li, Zigang,Sun, Jianwei
supporting information; experimental part, p. 1398 - 1401 (2012/06/01)
An efficient N-heterocyclic carbene (NHC)-catalyzed internal redox reaction of alkynals that bear a γ leaving group has been developed. This process provides a new access to a range of allenoates in good yields. Preliminary results demonstrate that the en
