1360744-06-4Relevant academic research and scientific papers
Efficient total synthesis of marine alkaloid (-)-nakadomarin A
Cheng, Bin,Wu, Fufang,Yang, Xiaobao,Zhou, Yuedong,Wan, Xiaolong,Zhai, Hongbin
, p. 12569 - 12572 (2011)
Z's top: For the total synthesis of the marine alkaloid (-)-nakadomarin A, (-)-camphorsulfonic acid assisted, Z-selective, olefin RCM of a monoamine (less polar) rather than a diamine (more polar) was found to be highly practical for constructing the F ring. The ABCD-tetracyclic core was assembled through a novel efficacious PtCl2-promoted cascade reaction sequence (see scheme).
