1360873-01-3

Basic information

• Product Name: C₆₂H₉₆O₁₁Si₂
• Synonyms: C₆₂H₉₆O₁₁Si₂
• CAS NO: 1360873-01-3
• Molecular Weight: 1073.61
• Mol File: 1360873-01-3.mol

Chemical Properties

• CAS DataBase Reference: C₆₂H₉₆O₁₁Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₆₂H₉₆O₁₁Si₂(1360873-01-3)
• EPA Substance Registry System: C₆₂H₉₆O₁₁Si₂(1360873-01-3)

Safety Data

• Hazardous Substances Data: 1360873-01-3(Hazardous Substances Data)

Upstream product

• 1028432-58-7 C₄₈H₆₅O₈PSi₂ 
• 1360872-79-2 C₂₆H₄₀O₇ 

Downstream Products

• 1360873-02-4 C₆₂H₉₆O₁₂Si₂ 
• 1360873-10-4 C₆₂H₉₈O₁₂Si₂ 
• 1028432-83-8 C₅₅H₁₀₀O₉Si₃ 
• 1028432-81-6 C₅₆H₁₀₂O₉SSi₃ 
• 1028433-12-6 C₃₈H₆₀O₉S 
• 1028433-10-4 C₃₆H₅₆O₁₀ 
• 1360873-12-6 C₃₆H₅₆O₁₀ 

Relevant articles and documents

Total synthesis of (-)-brevenal: A streamlined strategy for practical synthesis of polycyclic ethers

We describe a streamlined strategy for the practical synthesis of trans-fused polycyclic ethers and its application to a concise total synthesis of (-)-brevenal, a new pentacyclic polyether natural product with intriguing biological activities. The B-, D-, and E-rings were constructed by TEMPO/PhI(OAc)2-mediated oxidative lactonization of the corresponding 1,6-diols, with minimal need for manipulation of oxygen functionalities. The B- and E-ring lactones were appropriately functionalized by Suzuki-Miyaura coupling of lactone-derived enol phosphates and subsequent stereoselective hydroboration. The A-ring was formed by our mixed thioacetalization methodology. The AB- and DE-ring fragments were assembled through Suzuki-Miyaura coupling, and the C-ring was forged in the same manner as that for the A-ring. More than two grams of the pentacyclic polyether core of (-)-brevenal have been synthesized by the synthetic route developed in this study.