1360949-97-8

Basic information

• Product Name: Chloro(3-phenylindenyl)bis(triphenylphosphine)rutheniuM(II), Min. 98%
• Synonyms: Chloro(3-phenylindenyl)bis(triphenylphosphine)rutheniuM(II), Min. 98%;Chloro(1-phenylindenyl)bis(triphenylphosphine)ruthenium(II), min. 98%;Chloro(1-phenylindenyl)bis(triphenylphosphine)
• CAS NO: 1360949-97-8
• Molecular Formula: C₅₁H₄₁ClP₂Ru
• Molecular Weight: 852.341762
• Mol File: 1360949-97-8.mol
• Article Data: 3

Chemical Properties

• Appearance: red-brown/solid
• CAS DataBase Reference: Chloro(3-phenylindenyl)bis(triphenylphosphine)rutheniuM(II), Min. 98%(CAS DataBase Reference)
• NIST Chemistry Reference: Chloro(3-phenylindenyl)bis(triphenylphosphine)rutheniuM(II), Min. 98%(1360949-97-8)
• EPA Substance Registry System: Chloro(3-phenylindenyl)bis(triphenylphosphine)rutheniuM(II), Min. 98%(1360949-97-8)

Safety Data

• Hazardous Substances Data: 1360949-97-8(Hazardous Substances Data)

Usage

Reaction

Efficient, ruthenium-catalyzed S-S, S-Si, and S-B bond forming reactions. Chemoselective oxidation of secondary alcohols to ketones. Ruthenium complex used as an efficient transfer hydrogenation catalyst. Catalyst for the racemization of chiral alcohols.

Upstream product

• 15529-49-4 tris(triphenylphosphine)ruthenium(II) chloride 
• 3923-52-2 1,1-diphenyl-2-propyn-1-ol 

Downstream Products

• 1612883-71-2 [RuH2(PPh3)(η⁵-3-phenylindenyl)(SiPh3)] 
• 1612883-69-8 [RuH2(PPh3)(η⁵-3-phenylindenyl)(SiMePh2)] 
• 1612883-68-7 [RuH2(PPh3)(η⁵-3-phenylindenyl)(SiMe2Ph)] 
• 1612883-67-6 [RuH2(PPh3)(η⁵-3-phenylindenyl)(SiOEt3)] 
• 1612883-66-5 [RuH₂(SiEt₃)(PPh₃)(3-phenylindenyl)] 
• 1434055-89-6 [RuH(η⁵-(3-phenyl)indenyl)(PPh₃)₂] 

Relevant articles and documents

Chemoselective oxidation of secondary alcohols using a ruthenium phenylindenyl complex

A straightforward catalytic alcohol oxidation procedure using the recently reported complex [RuCl(PPh3)2(3-phenylindenyl)] (1) with KHMDS as cocatalyst, in acetone as the oxidant, is reported. Complex 1 shows remarkable chemoselectivity in oxidizing secondary alcohols to ketones.

From olefin metathesis catalyst to alcohol racemization catalyst in one step

Easy as π: An unusual indenylidene to I·5- indenyl rearrangement of a ruthenium catalyst has been observed. The resulting complex is the formal decomposition product of an olefin metathesis precatalyst that displays exceptional activity in the