1612883-66-5Relevant academic research and scientific papers
Ruthenium catalysed C-H bond borylation
Fernández-Salas, José A.,Manzini, Simone,Piola, Lorenzo,Slawin, Alexandra M. Z.,Nolan, Steven P.
, p. 6782 - 6784 (2014)
An easily prepared series of phenylindenyldihydridosilyl ruthenium complexes (2a-2d) was obtained by reaction of tertiary silanes with the commercially-available [RuCl(3-phenylindenyl)(PPh3)2] (1). The [RuH2(3-phenylindeny
Regioselective ruthenium catalysed H-D exchange using D2O as the deuterium source
Piola, Lorenzo,Ferandez-Salas, Jos A.,Manzini, Simone,Nolan, Steven P.
, p. 8683 - 8688 (2014/12/10)
An efficient and convenient ruthenium catalysed method for a regiospecific H/D exchange using D2O is described. Organic moieties such as pyridine, oxazole, imidazole, pyrazole, ester, ketone and carboxylic acid have been found effective directing groups in this transformation. In addition, the deuteration of the enantiopure (S)-Ketoprofen leads to the incorporation of three deuterium atoms with retention of molecular chirality.
