136097-50-2

Upstream product

• 676-58-4 methylmagnesium chloride 
• 136066-58-5 3-(2-oxo-2-phenylacetoxy)-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 611-73-4 Benzoylformic acid 
• 136066-56-3 (1S,2R,5S,6R)-Tricyclo[4.2.1.0^2,5]non-7-en-3-ol 

Downstream Products

• 136066-60-9 (+/-)-3-<2-methyl-2-<(trimethylsilyl)oxo>-2-phenylacetoxy>-endo-tricyclo<4.2.1.0^2,5>non-7-ene 
• 136066-46-1 (+/-)-(E)-1-(2-hydroxy-2-methyl-2-phenylacetoxy)-1,3-butadiene 

Relevant academic research and scientific papers

Diene-dienophile hydrogen-bonding control of diels-alder reactions with dienes bearing a remote stereogenic center. Amplification of the receptor nature of dienes by conformational tuning leading to high diastereofacial discrimination

The Diels-Alder reactions of 1-(O-methylmandeloxy)butadiene and its analogues, bearing a remote stereogenic center, have been studied to elucidate the stereoselective control elements. Several model dienes (5a-5f) have been designed to enhance the facial